A three-dimensional accordion-like metal–organic framework: synthesis and unconventional oriented growth on a surface

カテゴリ:研究業績 

2016年4月1日

Authors:
T. Haraguchi, K. Otsubo, O. Sakata, S. Kawaguchi, A. Fujiwara, H. Kitagawa

Abstract:
We describe the synthesis and sorption properties of a new metal–organic framework (MOF), Fe(H2O)2(bpy)[Pt(CN)4]·H2O (bpy = 4,4′-bipyridine), with a three-dimensional accordion-like structure. Although crystalline oriented MOF thin films reported to date have been mainly limited to a layer-type structure, we succeeded in the fabrication of its crystalline oriented thin film.

Link:
Chem. Commun. 52 (2016) 6017 – 6020.
DOI: 10.1039/C6CC00056H

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